The initial concentration of $N_2O_5$ in the first order reaction,$N_2O_5 \rightarrow 2NO_{2(g)} + \frac{1}{2}O_{2(g)}$ was $1.24 \times 10^{-2} \ mol \ L^{-1}$ at $300 \ K$ temperature. The concentration of $N_2O_5$ after $60 \ min$ was $0.20 \times 10^{-2} \ mol \ L^{-1}.$ Calculate the rate constant of the reaction.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) For a first order reaction,the rate constant $k$ is given by the formula: $k = \frac{2.303}{t} \log \frac{[A]_0}{[A]_t}$
Given:
Initial concentration $[A]_0 = 1.24 \times 10^{-2} \ mol \ L^{-1}$
Final concentration $[A]_t = 0.20 \times 10^{-2} \ mol \ L^{-1}$
Time $t = 60 \ min$
Substituting the values:
$k = \frac{2.303}{60} \log \frac{1.24 \times 10^{-2}}{0.20 \times 10^{-2}}$
$k = \frac{2.303}{60} \log(6.2)$
$k = \frac{2.303}{60} \times 0.7924$
$k \approx 0.0304 \ min^{-1}$

Explore More

Similar Questions

Half life of a first order reaction is $20 \ min$. The time taken to reduce the initial concentration of reactant to $(1/10)^{th}$ is $\qquad$ (in $min$)

The half-life of a first-order reaction is $10 \ minutes$. If the initial concentration is $0.08 \ mol/L$ and at some instant the concentration is $0.01 \ mol/L$,then the time elapsed is ...... minutes.

The rate constant of a reaction is $k = 3.28 \times 10^{-4} \text{ s}^{-1}$. Find the order of the reaction.

The rate constant of a first order reaction is $15 \times 10^{-3} \ s^{-1}$. How many seconds will $5.0 \ g$ of this reactant take to reduce to $3.0 \ g$?

Sucrose decomposes in acid solution into glucose and fructose according to the first order rate law,with $t_{1/2} = 3.00 \ h$. What fraction of sample of sucrose remains after $8 \ h$ $?$

Difficult
View Solution

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo